Docality.com Logo
 
Dr. Amy  Gabriel  Md image

Dr. Amy Gabriel Md

707 Druid Rd E
Clearwater FL 33756
727 611-1439
Medical School: University Of Iowa College Of Medicine - 1999
Accepts Medicare: Yes
Participates In eRX: No
Participates In PQRS: No
Participates In EHR: No
License #: ME114380
NPI: 1902980717
Taxonomy Codes:
207V00000X

Request Appointment Information

Awards & Recognitions

About Us

Practice Philosophy

Conditions

Dr. Amy Gabriel is associated with these group practices

Medical Malpractice Cases

None Found

Medical Board Sanctions

None Found

Referrals

None Found

Publications

Energetics and mechanism for the deamination of lithiated cysteine. - The journal of physical chemistry. B
Lithium cation complexes with cysteine (Cys) are collisionally activated with xenon in a guided ion beam tandem mass spectrometer and observed to deaminate in addition to loss of the intact amino acid. Source conditions are found to influence the cross sections for these processes considerably, a result interpreted in terms of two isomers, Li(+)(Cys) and (NH(3))Li(+)(C(3)H(4)O(2)S). Quantum chemical calculations at the B3LYP/6-311G(d,p) level are used to explore the reaction mechanism for this fragmentation process in detail. A complete reaction coordinate surface for the process is elucidated, including all intermediates and transition states. Theoretical molecular parameters for the two isomers and for the rate-limiting transition state for deamination of Li(+)(Cys) are then used to analyze the threshold energies in the experimental data, providing experimental measurements of the energies of the transition state and various products. These experimental energies are compared with single point energies calculated at three different levels, B3LYP, B3P86, and MP2(full), using the 6-311+G(2d,2p) basis set with geometries and zero point energies calculated at the B3LYP/6-311G(d,p) level, as well as with additional calculations using basis sets that include core correlation on lithium. Good agreement between experiment and theory suggests that the reaction mechanisms have been reasonably elucidated and identifies the C(3)H(4)O(2)S deamination product as thiirane-carboxylic acid.

Map & Directions

707 Druid Rd E Clearwater, FL 33756
View Directions In Google Maps

Nearby Doctors

1601 South Highland Ave.
Clearwater, FL 33756
727 855-5437
300 Pinellas St Ms19a
Clearwater, FL 33756
727 627-7415
1055 S Fort Harrison Ave
Clearwater, FL 33756
727 477-7786
1106 Druid Rd South Ste 301
Clearwater, FL 33756
727 465-5681
613 S Myrtle Ave
Clearwater, FL 33756
727 414-4526
300 Pinellas St Ms 47
Clearwater, FL 33756
727 627-7908
1020 Lakeview Rd
Clearwater, FL 33756
727 611-1439
300 Pinellas St
Clearwater, FL 33756
727 986-6612
455 Pinellas St Suite 400
Clearwater, FL 33756
727 451-1991