Docality.com Logo
 
Dr. Breanna  Powell  Dds image

Dr. Breanna Powell Dds

750 Lincoln Ln Apartment 1603
Dearborn MI 48126
616 819-9637
Medical School: Other - Unknown
Accepts Medicare: No
Participates In eRX: No
Participates In PQRS: No
Participates In EHR: No
License #: 2901021366
NPI: 1831592344
Taxonomy Codes:
122300000X

Request Appointment Information

Awards & Recognitions

About Us

Practice Philosophy

Conditions

Medical Malpractice Cases

None Found

Medical Board Sanctions

None Found

Referrals

None Found

Publications

Rate-limiting step of the Rh-catalyzed carboacylation of alkenes: C-C bond activation or migratory insertion? - Journal of the American Chemical Society
Rhodium-catalyzed intramolecular carboacylation of alkenes, achieved using quinolinyl ketones containing tethered alkenes, proceeds via the activation and functionalization of a carbon-carbon single bond. This transformation has been demonstrated using RhCl(PPh(3))(3) and [Rh(C(2)H(4))(2)Cl](2) catalysts. Mechanistic investigations of these systems, including determination of the rate law and kinetic isotope effects, were utilized to identify a change in mechanism with substrate. With each catalyst, the transformation occurs via rate-limiting carbon-carbon bond activation for species with minimal alkene substitution, but alkene insertion becomes rate-limiting for more sterically encumbered substrates. Hammett studies and analysis of a series of substituted analogues provide additional insight into the nature of these turnover-limiting elementary steps of catalysis and the relative energies of the carbon-carbon bond activation and alkene insertion steps.© 2011 American Chemical Society

Map & Directions

750 Lincoln Ln Apartment 1603 Dearborn, MI 48126
View Directions In Google Maps

Nearby Doctors

7247 Schaefer Rd
Dearborn, MI 48126
313 843-3210
Henry Ford Health System 19401 Hubbard Drive
Dearborn, MI 48126
313 828-8330
Henry Ford Health System 19401 Hubbard Drive
Dearborn, MI 48126
313 828-8330
15846 Michigan Ave
Dearborn, MI 48126
313 811-1864
15700 Michigan Avenue
Dearborn, MI 48126
313 824-4334
5111 Auto Club Dr Suite 112
Dearborn, MI 48126
313 172-2000
5580 Nottingham Ct Apt 104
Dearborn, MI 48126
508 946-6333
13051 Osborne St Apt 608
Dearborn, MI 48126
313 787-7575
19401 Hubbard Dr Department Of Emergency Medicine
Dearborn, MI 48126
313 828-8100