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Dr. Brandon  Mitchell  Dc image

Dr. Brandon Mitchell Dc

12631 World Plaza Ln #54
Fort Myers FL 33907
239 362-2225
Medical School: Other - Unknown
Accepts Medicare: No
Participates In eRX: No
Participates In PQRS: No
Participates In EHR: No
License #: CH11359
NPI: 1801293204
Taxonomy Codes:
111N00000X

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Publications

Nuclear motion in the σ-bound regime of metal-H₂ complexes: [Mg(H₂)(n=1-6)]²⁺. - The journal of physical chemistry. A
The dynamic, quantum structure of [Mg(H2)(n=1-6)](2+)complexes is investigated via ab initio path integral molecular dynamics simulations. These complexes represent the strong, σ-complex regime of metal-H2 interactions and are representative of bonding motifs found in metal-organic frameworks. Significant nuclear motion within the coordination sphere is observed, even though the ligands remain largely intact. Quantum effects are found to be important in the H-H and metal-H2 stretch coordinates, but the remaining motion in the molecule is well represented by classical simulations. Nearly free rotation of the dihydrogen moiety is observed in all complexes. Statistical averages and distributions of structural parameters are found to deviate nontrivially from the same parameters in static, equilibrium structures.

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12631 World Plaza Ln #54 Fort Myers, FL 33907
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