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Dr. Benjamin  Kohn  Md image

Dr. Benjamin Kohn Md

120 Paradise Ln
Cocoa FL 32927
210 894-4385
Medical School: Other - Unknown
Accepts Medicare: No
Participates In eRX: No
Participates In PQRS: No
Participates In EHR: No
License #: ME 42370
NPI: 1659655249
Taxonomy Codes:
207N00000X

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Palladium-catalyzed annulation reactions for diastereoselective cyclopentene synthesis. - Organic letters
Palladium-catalyzed annulation reactions of conjugate acceptors and allenyl boronic ester provide substituted cyclopentenes in high yields and, where applicable, diastereoselectivities. This method provides rapid assembly of building blocks for natural product synthesis, including polycyclic lactone and lactam products. Reactions are hypothesized to initiate by conjugate addition of a nucleophilic propargylpalladium complex.© 2011 American Chemical Society
Palladium-catalyzed conjugate allylation reactions of alpha,beta-unsaturated N-acylpyrroles. - Organic letters
Conjugate allylation reactions of alpha,beta-unsaturated N-acylpyrroles using allylboronic ester are catalyzed by a palladium complex that is ligated by a bidentate N-heterocyclic carbene. A variety of functional groups are tolerated, and substrates functionalized with electron-withdrawing groups react to afford the highest yields of products. Regioselectivity for 1,4-allylation over 1,2-allylation is demonstrated, and mechanistic experiments are consistent with formation of nucleophilic allylpalladium intermediates.

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120 Paradise Ln Cocoa, FL 32927
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